A Comprehensive Survey of Cationic Iridium(III) Complexes Bearing Nontraditional Ligand Chelation Motifs
نویسندگان
چکیده
منابع مشابه
Cationic iridium(III) complexes bearing a bis(triazole) ancillary ligand.
Three new heteroleptic cationic iridium complexes of the form [Ir(C^N)(btl)](+), where btl = 1,1'-benzyl-4,4'-bi-1H-1,2,3-triazolyl and C^N = 2-phenylpyridine (ppyH) (1), 1-benzyl-4-phenyl-1H-1,2,3-triazole (phtl) (2) or 1-benzyl-4-(2,4-difluorophenyl)-1H-1,2,3-triazole (dFphtl) (3), were synthesized and isolated as their hexafluorophosphate (PF6(-)) salts and fully characterized. The single cr...
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هدف از این مطالعه طراحی یک روش کلی برای سنتز یک سری از کمپلکس های دو هسته ای متقارن سیکلومتاله شده پلاتین (ii) بوده که دارای یک لیگاند پل زن(1,2-bis[bis(pentafluoro-phenyl)phosphino]ethane),dfppe, است. از واکنش cis-[pt(r)2(sme2)2]، که در آنr= para-tolyl ، با یک اکی والان از لیگاند benzo[h]quinoline,bhq، در استون محصول [pt(r)(bhq)(sme2)] که در آن r= para-tolyl بدست می آید. همچنین از واکنش 5/0 اک...
Zirconium complexes bearing a tetradentate dipyrrolyl ligand.
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The first well defined cationic terminal hydrido rare earth complexes [(NCN)LnH(THF)(3)][BPh(4)] were isolated from THF, which on recrystallization from chlorobenzene gave reversibly the novel dicationic binuclear dihydride complexes [(NCN)Ln(μ-H)(THF)(2)](2)[BPh(4)](2).
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2013
ISSN: 1434-1948
DOI: 10.1002/ejic.201300476